|
|
flaviolin + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> 3,3''-biflaviolin + oxidized_ferredoxin + H2O
|
1.14.19.69
biflaviolin synthase
|
–
|
M
|
|
BRENDA:
BR48981
KEGG:
R08912
MetaCyc:
RXN-9932
|
|
|
|
flaviolin + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> 3,8''-biflaviolin + oxidized_ferredoxin + H2O
|
1.14.19.69
biflaviolin synthase
|
–
|
M
|
|
BRENDA:
BR48982
KEGG:
R08913
MetaCyc:
RXN-9933
|
|
|
|
geranyl_diphosphate + flaviolin + H+ <=> 3-linalylflaviolin + diphosphate
|
2.5.1.123
flaviolin linalyltransferase
2.5.1.125
7-geranyloxy-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione synthase
|
–
–
|
|
|
BRENDA:
BR51045;
BS426430
KEGG:
R10969
MetaCyc:
RXN-15421
|
|
|
|
flaviolin + NADH + H+ + O2 <=> mompain + NAD+ + H2O
|
1.14.13
|
–
|
M
|
|
MetaCyc:
RXN-15585
|
|
|
|
1,3,6,8-Tetrahydroxynaphthalene + O2 <=> flaviolin + H2O + H+
|
1.13.12
|
–
|
M
|
|
MetaCyc:
RXN-15586
|
|
|
|
1,3,6,8-Tetrahydroxynaphthalene + O2 <=> flaviolin + H2O + H+
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-9930
|
|
|
|
geranyl_diphosphate + flaviolin <=> diphosphate + 3-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-2,5,7-trihydroxynaphthalene-1,4-dione
|
2.5.1.124
6-linalyl-2-O,3-dimethylflaviolin synthase
2.5.1.125
7-geranyloxy-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione synthase
|
–
–
|
|
|
BRENDA:
BS426429
|
|
|
|
geranyl_diphosphate + flaviolin <=> diphosphate + 2-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-3,6,7-trihydroxynaphthalene-1,4-dione
|
2.5.1.124
6-linalyl-2-O,3-dimethylflaviolin synthase
|
–
|
|
|
BRENDA:
BS426432
|
|
|
|
4 flaviolin + 4 reduced_ferredoxin_[iron-sulfur]_cluster + 4 H+ + O2 <=> 3,3''-biflaviolin + 3,8''-biflaviolin + 4 oxidized_ferredoxin + 4 H2O
|
1.14.19.69
biflaviolin synthase
|
–
|
|
|
BRENDA:
BS397180
|
|
|
|
flaviolin + NADPH + H+ <=> cis-(3S,4R)-4-hydroxyscytalone + NADP+
|
1.1.1.B57
|
–
|
|
|
BRENDA:
BS441394
|
|